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This is the Valkyria Chronicles 4 ace list. Don't say we didn't warn you. 

All Aces in Valkyria Chronicles 4 are Imperial soldiers, though Secret Agent Saki appears to be an undercover agent actually employed by some country in the Far East. Unlike VC1 and VC3, many enemy aces also provide a CP for their faction and thus count as both a leader and an ace in the after mission report.

Something of note is that several Aces encountered throughout carry modified weapons with adjusted stats compared to their standard Imperial-only counterparts. The stats of the weapon they unlock do not necessarily match the one they use: indeed, some such as Cova the Peacock do not even unlock the same type of weapon they use (in his case he uses a VB GW 2 general-purpose Mortar but unlocks a VB GW 2B(e) anti-tank Mortar).

There is also a pseudo-Ace, Major Burke, who commands a Heavy Imperial Tank which uses his name as the unit name, but he is not counted as an Ace kill and does not have an item drop.

DLC weapons are not required to earn the "Excellence in Armament" Medal.

The DLCs "A United Front With Squad 7," "The Two Valkyria" and "Edy's Advanced Ops" do not contain Aces.

Storyline

Name Class Mission Drop
Thane the Cadet Scout-insignia Scout Chapter 2: The Liberation of Reine ZM Kar 1(e)
Volatile Monamor Shocktrooper-insignia Shocktrooper Chapter 3: Rangers in the Storm - Part 1 ZM MP 1(e)
Tankbuster Nämy Lancer-insignia Lancer Chapter 4: The Battle of Siegval - Part 2 VB PL 1(e)
Hawkeye Iris Sniper-insignia Sniper Chapter 4: The Battle of Siegval - Part 3 ZM SG 1(e)
Kajmir the Watcher Grenadier-insignia Grenadier Chapter 6: The Point of No Return VB GW 1(e)
Mash the Hunter Sniper-insignia Sniper Chapter 7: A March in the Snow - Part 1 ZM SG 2(e)
Lucky Seitz Tank-insignia Tank Commander Chapter 7: A March in the Snow - Part 2 Spring Drive (Cactus)
Supersonic Marath Scout-insignia Scout Elite Chapter 8: The Crystal Sea - Part 2 ZM Kar 3(e)
Toma the Magus Lancer-insignia Lancer Elite Chapter 9: The Winter Witch VB PL 3(e)
Cova the Peacock Grenadier-insignia Grenadier Elite Chapter 10: Under the Ice VB GW 2B(e)
Ette of the Icefield Tank-insignia Tank Commander Chapter 11: The Sea Fortress Firing Calculator (Glory)
Duke Allibert Lancer-insignia Lancer Elite Chapter 12: Midnight Run VB PL 1B(e)
Ixa the Medi-Killer Sniper-insignia Sniper Elite Chapter 13: Waiting for Springtime ZM SG 4(e)
The Kill Sergeant Shocktrooper-insignia Trooper Elite Chapter 14: Azure Flame ZM MP 4(e)
Matz the Cleaner Tank-insignia Tank Commander Chapter 15: A Reason to Fight - Part 1 Firing Calculator (Hafen)
Yorde the Poet Scout-insignia Scout Elite Chapter 15: A Reason to Fight - Part 2 ZM Kar 5(e)
Gambit Zanatos Shocktrooper-insignia Trooper Elite Chapter 16: Forseti's Judgment ZM MP 5(e)
Captain Terror Lancer-insignia Lancer Elite Chapter 17: The Final Choice - Part 1 VB PL 4(e)
Mash the Hunted Sniper-insignia Sniper Elite Chapter 17: The Final Choice - Part 2 ZM SG 5(e)

Squad Stories

The Squad Stories The Price of Skill, Mischief Makers, All the Single Ladies, Girl in the Iron Mask and A Chivalrous Heart do not contain Aces.

Name Class Mission Drop
Field Agent Mors Scout-insignia Scout Like Old Times ZM Kar 2(e)
Roaring Chanitz Shocktrooper-insignia Shocktrooper A Prayer for the Broken ZM MP 2(e)
Kanz the Acolyte Grenadier-insignia Grenadier Paragon Reluctant Solitude VB GW 7B(e)
Hirz the Demoman Grenadier-insignia Grenadier Honor, Pride, and Regret VB GW 3(e)
Killstreak Meier Sniper-insignia Sniper Worlds Apart ZM SG 3(e)
Secret Agent Saki Scout-insignia Scout Elite To Live Unbound ZM Kar 4(e)
Tank Officer Arker Tank-insignia Tank Commander Treading New Ground Reinforced Frame (Hafen)
Commandant Zorg Tank-insignia Tank Commander Legacies Left Spring Drive (Glory)
Maht the Mechanic Grenadier-insignia Grenadier Elite Love and Logic VB GW 4B(e)
Comrade Harasky Shocktrooper-insignia Shocktrooper Unfortunate Souls ZM MP 3(e)
Zivilyn the Bane Lancer-insignia Lancer Gambler's Ruin VB PL 2(e)
Instructor Zenas Scout-insignia Scout Paragon Soul of the Navy ZM Kar 6(e)

Normal Skirmish

Normal Skirmish 1 (Milt Outskirts) does not contain an Ace.

Name Class Mission Drop
Zuko the Prophet Scout-insignia Scout Reine ZM Kar 1(e)
Larz the Reaper Shocktrooper-insignia Shocktrooper Siegval Line 1 ZM MP 1(e)
Inspector Muratus Scout-insignia Scout Siegval Line 2 ZM Kar 2(e)
Chienö the Raider Shocktrooper-insignia Shocktrooper Snowy Mountain Trail ZM MP 2(e)
Yümad the Blade Shocktrooper-insignia Trooper Elite The Crystal Sea ZM MP 3(e)
Xeda the Operator Scout-insignia Scout Elite Warehouse District ZM Kar 3(e)
Nox the Listener Shocktrooper-insignia Trooper Elite Loweholm Urban Area ZM MP 4(e)
Keel the Chiliarch Scout-insignia Scout Elite Breaking Ice Shelf ZM Kar 4(e)
Quil the Gunsmith Scout-insignia Scout Elite Snowbound Island ZM Kar 5(e)

Hard Skirmish

Name Class Mission Drop
Tavyse the Beast Shocktrooper-insignia Trooper Paragon Into the Woods ZM MP 5(e)
Aizer the Bulwark Lancer-insignia Lancer Paragon Out of the Box VB PL 2B(e)
Ty the Immortal Shocktrooper-insignia Trooper Paragon Beneath the Frost ZM MP 6(e)
Loverboy Wagner Lancer-insignia Lancer Paragon Off the Rails VB PL 5(e)
Tucker the Heavy Grenadier-insignia Grenadier Paragon Through the Fire VB GW 5(e)
Nix the Marksman Sniper-insignia Sniper Paragon Across the Bridge ZM SG 6(e)
Fucasa the Artist Grenadier-insignia Grenadier Paragon Within the Ruins VB GW 6(e)
Hummel the Pyro Shocktrooper-insignia Trooper Paragon For the Centurion ZM MP 7(e)
Kaye the Traitor Scout-insignia Scout Paragon From the Capital ZM Kar 7(e)

Challenge Skirmish

Name Class Mission Drop
Unsinkable Énder Lancer-insignia Lancer Paragon A True Battlefield VB PL 3B(e)
Mash the Haunted Sniper-insignia Sniper Paragon The Dream Team ZM SG X(e)
Colonel Hale Tank-insignia Tank Commander Blitzkrieg on the Canal Reinforced Frame (Cactus)

Squad E, To the Beach! DLC

Name Class Mission Drop
Investigator Ichas Scout-insignia Scout Elite Raiding the Base Swimsuit (Claude)
Kent, War Reporter Grenadier-insignia Grenadier Elite Raiding the Base Swimsuit (Riley)
Gouache the Blitz Sniper-insignia Sniper Elite Raiding the Base Swimsuit (Kai)
Macho Tavaciel Shocktrooper-insignia Trooper Elite Raiding the Base Swimsuit (Raz)
Iron Wall Cattady Scout-insignia Scout Elite Bathing Suits and Bullets Swimsuit (Minerva)

A Captainless Squad DLC

Name Class Mission Drop
Solitary Zahl Sniper-insignia Sniper Elite A Sleuth of Bears ZM SG XD(e)
Valiant Condor Shocktrooper-insignia Trooper Elite Snowball Fight ZM MP XD(e)

Expert Skirmish DLC

Name Class Mission Drop
Calavera the Keen Scout-insignia Scout Paragon Hafen Escort ZM Kar X(e)
Warlord Kobatak Lancer-insignia Lancer Paragon Blitz Assault VB PL 6(e)
The Blood Knight Shocktrooper-insignia Trooper Paragon Escape from a Dire Situation ZM MP 8(e)
Ino the Crafty Sniper-insignia Sniper Paragon Struggle on the Bridge ZM SG X2(e)
Vice Chief Chemis Scout-insignia Scout Paragon A Night-Shrouded Liberation ZM Kar 8(e)
Machere the Wily Grenadier-insignia Grenadier Paragon Clash Between Elite Squads VB GW 8(e)

Navigation

v  e
Imperial Aces
Scout Thane the Cadet | Zuko the Prophet | Field Agent Mors | Inspector Muratus | Supersonic Marath | Xeda the Operator | Secret Agent Saki | Keel the Chiliarch | Yorde the Poet | Quil the Gunsmith | Instructor Zenas | Kaye the Traitor | Calavera the Keen | Vice Chief Chemis | Investigator Ichas | Iron Wall Cattady |
Shocktrooper Volatile Monamor | Larz the Reaper | Roaring Chanitz | Chienö the Raider | Comrade Harasky | Yümad the Blade | The Kill Sergeant | Nox the Listener | Gambit Zanatos | Tavyse the Beast | Ty the Immortal | Hummel the Pyro | The Blood Knight | Valiant Condor | Macho Tavaciel
Lancer Tankbuster Nämy | Zivilyn the Bane | Toma the Magus | Duke Allibert | Captain Terror | Aizer the Bulwark | Loverboy Wagner | Unsinkable Énder | Warlord Kobatak
Sniper Hawkeye Iris | Mash the Hunter | Killstreak Meier | Ixa the Medi-Killer | Mash the Hunted | Nix the Marksman | Mash the Haunted | Solitary Zahl | Ino the Crafty | Gouache the Blitz
Grenadier Kajmir the Watcher | Cova the Peacock | Hirz the Demoman | Maht the Mechanic | Tucker the Heavy | Fucasa the Artist | Kanz the Acolyte | Machere the Wily | Kent, War Reporter
Tank Tank Officer Arker | Lucky Seitz | Commandant Zorg | Ette of the Icefield | Matz the Cleaner | Colonel Hale


v  e
Valkyria Chronicles 4 Mission List
Chapter 00 | 01 | 02 | i1 | 03a | 03b | 04a | 04b | 04c | 05 | 06 | 07a | 07b | i2 | 08a | 08b | i3 | 09 | 10 | 11 | i4 | 12 | 13 | i5 | 14 | 15a | 15b | 16 | 17a | 17b | 18a | 18b | E
Squad Stories Like Old Times (Curtis, Laurent, Eileen) | A Prayer for the Broken (Godwin, Nico, Rosetta) | The Price of Skill (Neige, Aladdin, Leonhardt) | Mischief Makers (Emmy, Viola, Simon) | Reluctant Solitude (Louffe, Stahlschrott) | Honor, Pride, and Regret (Rebecca, Fleuret, Mabel) | Worlds Apart (Zaiga, Vancey, Gertrude) | All the Single Ladies (Millenia, Brittany, Rita) | To Live Unbound (Scott, Norid, Azusa) | Treading New Ground (Aulard, Miles, Dan) | Legacies Left (Keigel, Ryan, Ronald) | Girl in the Iron Mask (Ferrier, Jean, Stanley) | Love and Logic (Aoife, Jascha, Hanna) | Unfortunate Souls (Jimmy, Lily, Odin) | Gambler's Ruin (Jester, Teresa, Connor) | Soul of the Navy (Brian, André, Sergio) | A Chivalrous Heart (Minerva, Christel)
Skirmish Normal: 01 | 02 | 03 | 04 | 05 | 06 | 07 | 08 | 09 | 10
Hard: 01 | 02 | 03 | 04 | 05 | 06 | 07 | 08 | 09
Challenge: 01 | 02 | 03
Expert: 01 | 02 | 03 | 04 | 05 | 06
DLC 01 | 02 | 03 | 04
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